Arachne has CC out the yin-yang. Slow from her spiderlings and web, cripple also from her web, silence from her facenom, and a ranged pull + stun if you manage to land it. She's extremely good for ganking when you use all her tools correctly. Her passive isn't to be underestimated either. When stacked 3 times, it will eat through a good chunk of someone's health even if they manage to escape.
All Kali has going for her are sustain and a CC immunity ult, which is laughably weak if you build physicla protection since it doesn't proc Executioner stacks. Almost any other melee assassin, except maybe Bastet, are better picks.
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