I started with Neith, which seems to be her entire purpose of existence. You play her in the tutorial, so you try her first, and you obviously like her and keep playing her. She's really not OP, she's just EZ mode, so she's perfect as a first character.
Odin and Isis were the first two gods I bought, and I played both for a while before picking up Freya and taking her all the way to level 30 and god rank 10.
My first favorite god was Ares when he came out. His ult was so OP. There was no way to NOT be pulled and he could go twice as far with you twice as fast.
Then it was Guan Yu because he was so good with the Gem of Isolation before he became a physical God.
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